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Title
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirine
Source
Phosphorus, Sulfur & Silicon & the Related Elements
Date
2010
Author
Ishitsuka, Midori O.
;
Enoki, Haruka
;
Tsuchiya, Takahiro
;
Slanina, Zdenek
;
Mizorogi, Naomi
;
Nagase, Shigeru
;
Liu, Michael T. H.
;
Akasaka, Takeshi
Genre
Journal Article
Volume
185
Issue
5
Start Page
1124
DOI
10.1080/10426501003773464
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Title
Does Gd@C82 have an anomalous endohedral structure? Synthesis and ingle Crystal x-ray structure of the carbene adduct
Source
Journal of the American Chemical Society
Date
2008
Author
Akasaka, Takeshi
;
Kono, Takayoshi
;
Takematsu, Yuji
;
Nikawa, Hidefumi
;
Nakahodo, Tsukasa
;
Wakahara, Takatsugu
;
Ishitsuka, Midori O.
;
Tsuchiya, Takahiro
;
Maeda, Yutaka
;
Liu, Michael T. H.
;
Yoza, Kenji
;
Kato, Tatsuhisa
;
Yamamoto, Kazunori
;
Mizorogi, Naomi
;
Slanina, Zdenek
;
Nagase, Shigeru
Genre
Journal Article
Abstract
Abstract: We report here the results on single crystal X-ray crystallographic analysis of the Gd@C82 carbene adduct (Gd@C82(Ad), Ad =...
Volume
130
Issue
39
Start Page
12840
DOI
10.1021/ja802156n
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Title
Nanorods of endohedral metallofullerene derivative
Source
Journal of the American Chemical Society
Date
2008
Author
Tsuchiya, Takahiro
;
Kumashiro, Ryotaro
;
Tanigaki, Katsumi
;
Matsunaga, Yoichiro
;
Ishitsuka, Midori O.
;
Wakahara, Takatsugu
;
Maeda, Yutaka
;
Takano, Yuta
;
Aoyagi, Motoki
;
Akasaka, Takeshi
;
Liu, Michael T. H.
;
Kato, Tatsuhisa
;
Suenaga, Kazutomo
;
Jeong, Jong S.
;
Iijima, Sumio
;
Kimura, Fumiko
;
Kimura, Tsunehisa
;
Nagasev, Shigeru
Genre
Journal Article
Abstract
The article presents a research which discusses the preparation and characterization of the nanorods of the endohedral metallofullerene derivative...
Volume
130
Issue
2
Start Page
450
DOI
10.1021/ja710396n
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Title
Isolation and characterization of carbene derivatives of LaC82(Cs)
Source
Journal of Physical Chemistry A
Date
2008
Author
Akasaka, Takeshi
;
Kono, Takayoshi
;
Matsunaga, Yoichiro
;
Wakahara, Takatsugu
;
Nakahodo, Tsukasa
;
Ishitsuka, Midori
;
Maeda, Yutaka
;
Tsuchiya, Takahiro
;
Kato, Tatsuhias
;
Liu, Michael T.H.
;
Mizorogi, Naomi
;
Slanina, Zdenek
;
Nagase, Shigeru
Genre
Journal Article
Volume
112
Issue
6
Start Page
1294
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Title
Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene)
Source
Journal of the American Chemical Society
Date
2008
Author
Yamada, M.
;
Someya, C.
;
Wakahara, T.
;
Tsuchiya, T.
;
Maeda, Y.
;
Akasaka, T.
;
Yoza, K.
;
Horn, E.
;
Liu, Michael T. H.
;
Mizorogi, N.
;
Nagase, S.
Genre
Journal Article
Abstract
Abstract: The photochemical reaction of M2@C80 (M = La and Ce) with 2-adamantane-2,3'-[3H]-diazirine (1) affords the corresponding adducts by...
Volume
130
Issue
4
Start Page
1171
DOI
10.1021/ja073924w
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Title
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirine
Source
Tetrahedron Letters
Date
2007
Author
Liu, Michael T. H.
Genre
Journal Article
Start Page
6290
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Title
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivative
Source
Angewandte Chemie-International Edition
Date
2007
Author
Iiduka, Y.
;
Wakahara, T.
;
Nakajima, K.
;
Nakahodo, T.
;
Tsuchiya, T.
;
Maeda, Y.
;
Akasaka, T.
;
Yoza, K.
;
Liu, Michael T. H.
;
Mizorogi, N.
;
Nagase, S.
Genre
Journal Article
Volume
46
Issue
29
Start Page
5562
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Title
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe technique
Source
Tetrahedron Letters
Date
2007
Author
Ishitsuka, M. O.
;
Enoki, H.
;
Nikawa, H.
;
Wakahara, T.
;
Tsuchiya, T.
;
Akasaka, T.
;
Liu, Michael T. H.
Genre
Journal Article
Abstract
By employing C-60 as a chemical probe, the photolysis of benzylchlorodiazirine has been proposed to form carbene and the rearranged products via...
Volume
48
Issue
5
Start Page
859
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Title
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridyl
Subtitle
Synthesis, reaction mechanism, and effect of rotamerism
Source
European Journal of Organic Chemistry
Date
2005
Author
Bonneau, R.
;
Liu, Michael T. H.
Genre
Journal Article
Abstract
Phenylchlorocarbene, generated by photolysis or thermolysis of the phenylchlorodiazirine, reacts with 2,2'-bipyridyl to give, in alkane solvents,...
Issue
8
Start Page
1532
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Title
S-heterocyclic carbene with a disilane backbone
Source
Angewandte Chemie-International Edition
Date
2005
Author
Nikawa, H.
;
Nakahodo, T.
;
Tsuchiya, T.
;
Wakahara, T.
;
Rahman, G. M. A.
;
Akasaka, T.
;
Maeda, Y.
;
Liu, Michael T. H.
;
Meguro, A.
;
Kyushin, S.
;
Matsumoto, H.
;
Mizorogi, N.
;
Nagase, S.
Genre
Journal Article
Volume
44
Issue
46
Start Page
7567
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Title
Structural determination of metallofuIlerene SC3C82 revisited
Subtitle
A surprising finding
Source
Journal of the American Chemical Society
Date
2005
Author
Liduka, Y.
;
Wakahara, T.
;
Nakahodo, T.
;
Tsuchiya, T.
;
Sakuraba, A.
;
Maeda, Y.
;
Akasaka, T.
;
Yoza, K.
;
Horn, E.
;
Kato, T.
;
Liu, Michael T. H.
;
Mizorogi, N.
;
Kobayashi, K.
;
Nagase, S.
Genre
Journal Article
Volume
127
Issue
36
Start Page
12500
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Title
Isolation and characterization of a carbene derivative of La@C-82
Source
Journal of the American Chemical Society
Date
2004
Author
Maeda, Y.
;
Matsunaga, Y.
;
Wakahara, T.
;
Takahashi, S.
;
Tsuchiya, T.
;
Ishitsuka, M. O.
;
Hasegawa, T.
;
Akasaka, T.
;
Liu, Michael T. H.
;
Kokura, K.
;
Horn, E.
;
Yoza, K.
;
Kato, T.
;
Okubo, S.
;
Kobayashi, K.
;
Nagase, S.
;
Yamamoto, K.
Genre
Journal Article
Volume
126
Issue
22
Start Page
6858
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Title
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbene
Source
Journal of Physical Chemistry A
Date
2004
Author
Bonneau, R.
;
Collado, D.
;
Dalibart, M.
;
Liu, Michael T. H.
Genre
Journal Article
Abstract
The analysis of the time-resolved UV-vis absorption spectra of the 2-vinylpyridinium ylide of phenylchlorocarbene, measured by laser-flash...
Volume
108
Issue
7
Start Page
1312
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Title
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe technique
Source
Tetrahedron Letters
Date
2004
Author
Ishitsuka, M. O.
;
Niino, Y.
;
Wakahara, T.
;
Akasaka, T.
;
Liu, Michael T. H.
;
Kobayashi, K.
;
Nagase, S.
Genre
Journal Article
Abstract
C-60 acts as a mechanistic probe for the formation of carbene and for the rearranged product via the excited state in the photolysis of 3-t-butyl-3...
Volume
45
Issue
33
Start Page
6321
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Title
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates
Source
Tetrahedron Letters
Date
2003
Author
Romashin, Y. N.
;
Liu, Michael T. H.
;
Hill, B. T.
;
Platz, M. S.
Genre
Journal Article
Abstract
Reaction of adamantylidene and phenylcarbene with ethylthiol, ethylene dithiol, allylethylsulfide, allylphenylsulfide, and trimethylenesulfide...
Volume
44
Issue
34
Start Page
6519
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Title
Effect of substituents on the thermal decomposition of diazirines
Subtitle
Experimental and computational studies
Source
Journal of Organic Chemistry
Date
2003
Author
Liu, Michael T. H.
;
Choe, Y. K.
;
Kimura, M.
;
Kobayashi, K.
;
Nagase, S.
;
Wakahara, T.
;
Niino, Y.
;
Ishitsuka, M. O.
;
Maeda, Y.
;
Akasaka, T.
Genre
Journal Article
Abstract
The thermal decomposition of phenylehlorodiazirine (1), phenyl-n-butyldiazirine (2), and 2-adamantane-2,3'-[3H] diazirine (3) has been studied in...
Volume
68
Issue
19
Start Page
7471
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Title
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridine
Subtitle
does an indolizine chromophore inhibit the photolysis of a diazirine?
Source
Journal of Photochemistry and Photobiology A-Chemistry
Date
2003
Author
Bonneau, R.
;
Collado, D.
;
Liu, Michael T. H.
Genre
Journal Article
Abstract
The photolysis of m-phenylene-bis(chlorodiazirine) in the presence of 2-vinylpyridine (VP) yields the m-phenylene-bis(indolizine) by a mechanism...
Volume
161
Issue
1
Start Page
43
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Title
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine
Subtitle
Carbene, diazo and rearrangement in excited state
Source
Journal of the American Chemical Society
Date
2002
Author
Wakahara, T.
;
Niino, Y.
;
Kato, T.
;
Maeda, Y.
;
Akasaka, T.
;
Liu, Michael T. H.
;
Kobayashi, K.
;
Nagase, S.
Genre
Journal Article
Abstract
C-60 acts as a mechanistic probe for the formation of carbene, diazo compound, and for the rearranged product via the excited state in the...
Volume
124
Issue
32
Start Page
9465
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Title
Photochemical decomposition of pyrazoline produced in the reaction of C60 with Diazoadamantane
Source
ITE Letters on Batteries, New Technologies & Medicine
Date
2002
Author
Niino, Y.
;
Wakahara, T.
;
Akasaka, T.
;
Liu, Michael T. H.
Genre
Journal Article
Volume
3
Issue
1
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Title
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulide
Subtitle
determination of rate parameters by laser flash photolysis
Source
Tetrahedron Letters
Date
2001
Author
Romashin, Y. N.
;
Liu, Michael T. H.
;
Bonneau, R.
Genre
Journal Article
Abstract
Reaction of arylchlorodiazirines with trimethylenesulfide gives a mixture of aryldi(3-chloropropyl)thioacetal and aryl(2-propenyl)(3-chloropropyl...
Volume
42
Issue
2
Start Page
207
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